Regiospecific C–H Bond Activation: Reactivity Study of N-Heterocyclic Silylene toward Ambidentate Phosphorus Ylide
| Autor: | Jakob Hey, Sankaranarayana Pillai Sarish, Ramachandran Azhakar, Herbert W. Roesky, Dietmar Stalke |
|---|---|
| Rok vydání: | 2011 |
| Předmět: |
chemistry.chemical_classification
C h bond 010405 organic chemistry Phosphorus Organic Chemistry Silylene chemistry.chemical_element 010402 general chemistry Photochemistry 01 natural sciences Medicinal chemistry 0104 chemical sciences Inorganic Chemistry chemistry.chemical_compound chemistry Ylide Elemental analysis C -H Bond Activation x-ray structural analysis Reactivity (chemistry) Physical and Theoretical Chemistry |
| Zdroj: | Organometallics. 30:2897-2900 |
| ISSN: | 1520-6041 0276-7333 |
| DOI: | 10.1021/om200308u |
| Popis: | The reaction of two highly reactive species, the silylene [CH{C(Me)NAr}- {C(dCH2)NAr}Si] (L, Ar = 2,6-iPr2C6H3) and the phosphorus ylide MeC(O)CHPPh3, resulted in the formation of 1, involving regiospecific Calkyl H bond activation. Compound 1 was characterized by elemental analysis and multinuclear NMR and unambiguously by single-crystal X-ray structural analysis. peerReviewed |
| Databáze: | OpenAIRE |
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