The (P4HMes4)- Anion: Lability, Fluxionality, and Structural Ambiguity (Mes = 2,4,6-Me3C6H2)

Autor:	Santiago Gómez-Ruiz, Robert Wolf, Joachim Reinhold, Evamarie Hey-Hawkins, Winfried Böhlmann
Rok vydání:	2006
Předmět:	Inorganic Chemistry Proton Lability Stereochemistry Chemistry Structural ambiguity Physical and Theoretical Chemistry Ion
Zdroj:	Inorganic Chemistry. 45:9107-9113
ISSN:	1520-510X 0020-1669
DOI:	10.1021/ic060795w
Popis:	The synthesis and structural characterization of the tetramesityltetraphosphanide anion, (P4HMes4)- (1), is described. It is shown that 1 partially decomposes in solution and displays an unsymmetrical structure in which, depending on conditions, the proton may or may not fluctuate between the terminal P atoms of the P4 chain.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1680593506edd5bf175e9d33309c6c1b https://doi.org/10.1021/ic060795w Zobrazit plný text záznamu