Determination of Fluopicolide in Livestock Products and Seafood by LC-MS/MS
| Autor: | Naoko Sakai, Masaki Hayashi, Takeo Sasamoto, Hiroshi Koike, Ichiro Takano, Itoko Baba, Kyoko Kamijo, Maki Kobayashi, Harunori Otani, Tetsuya Shindo, Satoru Nemoto |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Livestock
Silylation Formic acid Sodium Eggs chemistry.chemical_element 030204 cardiovascular system & hematology 010501 environmental sciences 01 natural sciences 03 medical and health sciences chemistry.chemical_compound 0302 clinical medicine Tandem Mass Spectrometry Acetone Animals 0105 earth and related environmental sciences Detection limit Chromatography Silica gel business.industry Pesticide Residues food and beverages General Medicine Honey Fungicides Industrial Meat Products Milk chemistry Seafood Benzamides Fluopicolide Cattle business Chickens Food Analysis Chromatography Liquid |
| Zdroj: | Shokuhin eiseigaku zasshi. Journal of the Food Hygienic Society of Japan. 57(4) |
| ISSN: | 1882-1006 |
| Popis: | An analytical method for the determination of fluopicolide in livestock products and seafood was developed using LC-MS/MS. Sodium chloride was added to livestock products and seafood samples and fluopicolide was extracted twice with acetone after acidification with formic acid. The fat from the crude extract was removed using a macroporous diatomaceous earth column, followed by purification with a combination of mini-columns of GC (graphite carbon) and PSA (ethylenediamine-N-propyl silylation silica gel). The average recovery (n=5) of fluopicolide from 10 types of livestock products and seafood (cattle fat, cattle liver, cattle muscle, chicken, eel, egg, freshwater clam, honey, milk and salmon) spiked at the MRLs or at the uniform limit (0.01 ppm) was 96-100%, with a relative standard deviation of 2.3-6.2%. The limit of quantitation of the developed method was calculated to be 0.01 mg/kg. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|