In defence of negative temperature
Autor: | J. Poulter |
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Rok vydání: | 2015 |
Předmět: |
Statistical Mechanics (cond-mat.stat-mech)
Entropy (statistical thermodynamics) H-theorem Gibbs paradox Configuration entropy Maximum entropy thermodynamics FOS: Physical sciences Entropy in thermodynamics and information theory computer.software_genre 01 natural sciences 010305 fluids & plasmas symbols.namesake 0103 physical sciences Boltzmann constant symbols Data mining Statistical physics 010306 general physics Boltzmann's entropy formula computer Condensed Matter - Statistical Mechanics Mathematics |
DOI: | 10.48550/arxiv.1508.00350 |
Popis: | This pedagogical comment highlights three misconceptions concerning the usefulness of the concept of negative temperature; being derived from the usual, often termed Boltzmann, definition of entropy. First, both the Boltzmann and Gibbs entropies must obey the same thermodynamic consistency relation. Second, the Boltzmann entropy does obey the second law of thermodynamics. Third, there exists an integrating factor of the heat differential with both definitions of entropy. Comment: 6 pages. Second version. Updated and polished |
Databáze: | OpenAIRE |
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