(−)-Dimethyl 3,3′-diphenyl-2,2′-[pyridine-2,6-diylbis(carbonylimino)]dipropanoate
| Autor: | Guoxin Sun, Yu Cui, Shaohong Yin, Yanju Zhang, Guangming Xia |
|---|---|
| Rok vydání: | 2009 |
| Předmět: |
chemistry.chemical_classification
Hydrogen bond Chemistry General Chemistry Crystal structure Dihedral angle Condensed Matter Physics Ring (chemistry) Bioinformatics Organic Papers Medicinal chemistry Amino acid chemistry.chemical_compound Pyridine General Materials Science Amine gas treating Derivative (chemistry) |
| Zdroj: | Acta Crystallographica Section E: Structure Reports |
| ISSN: | 1600-5368 |
| DOI: | 10.1107/s1600536809023721 |
| Popis: | The title compound, C(27)H(27)N(3)O(6), a bis-amide derivative, is also a chiral amino acid ester with l-phenyl-alanine methyl ester groups as amine substituents. The pyridine ring is oriented at dihedral angles of 89.69 (3) and 62.95 (3)° with respect to the phenyl rings, while the dihedral angle between the phenyl rings is 60.76 (3)°. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains. One of the carbonyl O atoms and one of the meth-oxy CH(3) groups are disordered over two positions. The O atom was refined with occupancies of 0.69 (13) and 0.31 (13), while C and H atoms were refined with occupancies of 0.69 (8) and 0.31 (8). |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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