Reactor scale simulations of ALD and ALE: ideal and non-ideal self-limited processes in a cylindrical and a 300 mm wafer cross-flow reactor
| Autor: | Jeffrey W. Elam, Joseph A. Libera, Angel Yanguas-Gil |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Condensed Matter - Materials Science
Materials science Fluid Dynamics (physics.flu-dyn) Materials Science (cond-mat.mtrl-sci) FOS: Physical sciences Surfaces and Interfaces Quartz crystal microbalance Mechanics Applied Physics (physics.app-ph) Physics - Applied Physics Physics - Fluid Dynamics Condensed Matter Physics Surfaces Coatings and Films Atomic layer deposition chemistry.chemical_compound Adsorption chemistry Etching (microfabrication) Titanium dioxide Titanium tetrachloride Wafer Physics::Chemical Physics Layer (electronics) |
| Popis: | We have developed a simulation tool to model self-limited processes such as atomic layer deposition and atomic layer etching inside reactors of arbitrary geometry. In this work, we have applied this model to two standard types of cross-flow reactors: a cylindrical reactor and a model 300 mm wafer reactor, and explored both ideal and non-ideal self-limited kinetics. For the cylindrical tube reactor the full simulation results agree well with analytic expressions obtained using a simple plug flow model, though the presence of axial diffusion tends to soften growth profiles with respect to the plug flow case. Our simulations also allowed us to model the output of in-situ techniques such as quartz crystal microbalance and mass spectrometry, providing a way of discriminating between ideal and non-ideal surface kinetics using in-situ measurements. We extended the simulations to consider two non-ideal self-limited processes: soft-saturating processes characterized by a slow reaction pathway, and processes where surface byproducts can compete with the precursor for the same pool of adsorption sites, allowing us to quantify their impact in the thickness variability across 300 mm wafer substrates. |
| Databáze: | OpenAIRE |
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