Surface Modification of Cellulose Nanocrystals with Lactone Monomers via Plasma-Induced Polymerization and Their Application in ABS Nanocomposites
| Autor: | Ilse Magaña, Guadalupe Neira, Ediberto Guzmán, Ramón Díaz de León, Luis Valencia, Alejandro Díaz Elizondo, Adali Castañeda Facio, Ricardo López González |
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| Jazyk: | angličtina |
| Rok vydání: | 2021 |
| Předmět: |
Nanocomposite
Materials science Polymers and Plastics Organic chemistry Nanoparticle Context (language use) General Chemistry δ-decalactone Article chemistry.chemical_compound QD241-441 Monomer Polymerization chemistry Chemical engineering Nanocrystal Surface modification Fourier transform infrared spectroscopy plasma-induced polymerization surface modification ε-caprolactone cellulose nanocrystals |
| Zdroj: | Polymers Volume 13 Issue 16 Polymers, Vol 13, Iss 2699, p 2699 (2021) |
| ISSN: | 2073-4360 |
| DOI: | 10.3390/polym13162699 |
| Popis: | The growing concern for environmental problems has motivated the use of materials obtained from bio-based resources such as cellulose nanocrystals which have a promising application acting as fillers or reinforcements of polymeric materials. In this context, in this article, plasma-induced polymerization is proposed as a strategy to modify nanocrystals at different plasma power intensities using ε-caprolactone and δ-decalactone to improve their compatibility with polymeric matrices. The characterization was carried out using techniques such as FTIR, TGA, XRD, XPS, and AFM, with which a successful functionalization was demonstrated without altering the inherent properties of the nanocrystals. The preparation of ABS nanocomposites was carried out with the modified nanoparticles and the evaluation of the mechanical properties indicates an increase in Young’s modulus and yield stress under certain concentrations of modified cellulose nanocrystals. |
| Databáze: | OpenAIRE |
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