O-Vinyldiaryl- and O-Vinylaryl(hetaryl)ketoximes: A Breakthrough in O-Vinyloxime Chemistry

Autor:	Alexander M. Vasil'tsov, Al'bina I. Mikhaleva, Elena Yu. Schmidt, A. V. Afonin, Ludmila V. Morozova, Alexey B. Zaitsev, Boris A. Trofimov, Igor A. Ushakov
Rok vydání:	2003
Předmět:	chemistry.chemical_compound Monomer chemistry Acetylene Group (periodic table) Aryl Organic Chemistry Drug Discovery Superbase Organic chemistry Organic synthesis General Medicine Biochemistry
Zdroj:	ChemInform. 34
ISSN:	1522-2667 0931-7597
Popis:	O -Vinyldiarylketoximes and O -vinylaryl(hetaryl)ketoximes, a novel family of stable O -vinyloximes, are synthesized by a straightforward, unusually fast vinylation of diarylketoximes and aryl(hetaryl)ketoximes with acetylene in a superbase system of KOH–DMSO (60–80°C, 5–7 min). Yields of up to 90% were obtained, thus introducing into organic synthesis a new group of highly promising building blocks and monomers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1495a1af511a665721a636ad3491a41b https://doi.org/10.1002/chin.200314092 Zobrazit plný text záznamu Plný text