[1-Me-1-closo-SnB11 H-11](-) as a potential weakly coordinating anion: Synthesis of Rh(PPh3)(2)(1-Me-closo-SnB11 H-11) and comparisons with Rh(PR3)(2) (1-H-closo-CB11 H-(11))

Autor:	Thomas P. H. Player, Eduardo Molinos, Giuseppe D. Ruggerio, Andrew S. Weller, Gabriele Kociok-Köhn
Jazyk:	angličtina
Rok vydání:	2006
Předmět:	chemistry.chemical_classification Chemistry Stereochemistry Heteroatom Solid-state Salt (chemistry) General Chemistry Medicinal chemistry Ion
Zdroj:	HETEROATOM CHEMISTRY. 17(3)
ISSN:	1098-1071 1042-7163
Popis:	The closo-stannaborane salt [Rh(PPh3)2-(nbd)][1-Me-1-closo-SnB11H11] reacts with H2 in CH2 Cl2 solution to afford the contact ion-pair Rh(PPh3)2(1-Me-closo-SnB11H11), which has been characterized in solution and the solid state by X-ray diffraction. © 2006 Wiley Periodicals, Inc. Heteroatom Chem 17:174–180, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20218
Databáze:	OpenAIRE
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