Bi- and trimetallic rare-earth–palladium complexes ligated by phosphinoamides
| Autor: | Franziska Völcker, Karin Fink, Konstantinos D. Vogiatzis, Peter W. Roesky, Felix M. Mück |
|---|---|
| Rok vydání: | 2015 |
| Předmět: |
Quantum chemical
Rare earth Metals and Alloys chemistry.chemical_element General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Metal Crystallography chemistry Computational chemistry visual_art Materials Chemistry Ceramics and Composites visual_art.visual_art_medium Palladium |
| Zdroj: | Chemical Communications. 51:11761-11764 |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c5cc03944d |
| Popis: | The synthesis of the heterometallic early-late 4d/4f bi- and trinuclear phosphinoamido Ln-Pd(0) complexes [(Ph2PNHPh)Pd{μ-(Ph2PNPh)}3Ln(μ-Cl)Li(THF)3] (Ln = Y, Lu) and [Li(THF)4][{(Ph2PNHPh)Pd}2{μ-(Ph2PNPh)}4Ln] (Ln = Y, Lu) is described. The latter compounds are the first early-late trimetallic phosphinoamido complexes. Although the metal atoms are forced into close proximity by the phosphinoamido ligands, quantum chemical calculations show only weak metal-to-metal interactions. |
| Databáze: | OpenAIRE |
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