Excursions of Synthetic Organic Chemists to the World of Oligomers and Polymers

Autor:	Seebach, D., Beck, A. K., Magnus Rueping, Schreiber, J. V., Sellner, H.
Jazyk:	němčina
Rok vydání:	2001
Předmět:	Chemistry Beta-peptides Polymer-bound chiralligands Oligo-(3-hydroxybutanoates) General Medicine General Chemistry Dendritic cross-linkers Secondary structures QD1-999
Zdroj:	CHIMIA, Vol 55, Iss 3 (2001) ResearcherID Scopus-Elsevier
ISSN:	2673-2424 0009-4293
Popis:	The activities of a group devoted to organic synthesis in the field of polymer and oligomer chemistry have led to new types of dendritic cross-linking compounds for the polymerization of styrene to give high-quality materials. In addition the synthesis of uniform ('monodisperse'), high-molecular weight oligomers of 3-hydroxybutanoic acid provided samples for investigations to prove the hypothesis that polyhydroxybutyrates are natural ion-channel components in living organisms. Oligomers of ?-amino acids were prepared and have been shown to form all the secondary structures known from natural peptides and proteins (composed of ?-amino acids), i.e. helices, pleated sheets, turns, hair pins and stacks with properties differing fundamentally from those of the natural analogs.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1442d751002cc62372f7f457c29bfe2e https://chimia.ch/chimia/article/view/3363 Zobrazit plný text záznamu