Polyaromatic ribbons from oligo-alkynes via selective radical cascade: stitching aromatic rings with polyacetylene bridges

Autor:	Philip M. Byers, Igor V. Alabugin
Rok vydání:	2012
Předmět:	Aromatization Functionalized graphene Aromaticity General Chemistry Conjugated system Photochemistry Biochemistry Catalysis Polyacetylene chemistry.chemical_compound Colloid and Surface Chemistry chemistry Cascade Intramolecular force Yield (chemistry)
Zdroj:	Journal of the American Chemical Society. 134(23)
ISSN:	1520-5126
Popis:	Selective radical generation in conjugated oligomeric o-aryleneethynylenes initiates an intramolecular cascade which involves five fast radical cyclizations followed by aromatization via a 1,5-H shift with a >93% yield per step. This radical cascade transformation opens a new avenue for the systematic and controlled preparation of functionalized graphene nanoribbons where, potentially, each of the peripheral aromatic rings can be different.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::143792aee53e678105d8549b4f59190d https://pubmed.ncbi.nlm.nih.gov/22616674 Zobrazit plný text záznamu