Photoinduced Charge Accumulation and Prolonged Multielectron Storage for the Separation of Light and Dark Reaction

Autor:	Benjamin Dietzek, Bianca Seidler, Marco Rosenkranz, Martin Schulz, Grace A. Lowe, Nina Hagmeyer, Johannes G. Vos, Frerk Wehmeyer, Carsten Streb, Alexey A. Popov
Rok vydání:	2020
Předmět:	Hydrogen business.industry chemistry.chemical_element Charge (physics) Protonation General Chemistry 010402 general chemistry Photochemistry Solar energy 01 natural sciences Biochemistry Catalysis 0104 chemical sciences Electron transfer Colloid and Surface Chemistry chemistry Physics::Space Physics Photocatalysis Astrophysics::Solar and Stellar Astrophysics Dark reaction Astrophysics::Earth and Planetary Astrophysics business Computer Science::Databases
Zdroj:	Journal of the American Chemical Society. 142:15722-15728
ISSN:	1520-5126 0002-7863
Popis:	The utilization of solar energy is restricted by the intermittent nature of solar influx. We present novel noble-metal free complexes that can be photochemically charged in the presence of sacrificial electron donors and remain stable in its charged form for over 14 h. This allows the doubly reduced Cu(I) 4
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::142cae08507af68240c1afa8f9f6050d https://doi.org/10.1021/jacs.0c03779 Zobrazit plný text záznamu