Solvent effects on the crystal structure of silver pentacyanocyclopentadienide: supramolecular isomerism and solvent coordination
| Autor: | Karlheinz Sünkel, Dietmar Reimann, Patrick R. Nimax |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Supramolecular chemistry macromolecular substances Crystal structure Polymer 010402 general chemistry 01 natural sciences 0104 chemical sciences Inorganic Chemistry Solvent Crystallography chemistry Yield (chemistry) bacteria Molecule Polar Solvent effects |
| Zdroj: | Dalton transactions (Cambridge, England : 2003). 47(25) |
| ISSN: | 1477-9234 |
| Popis: | Several coordination polymers of silver(i)-pentacyanocyclopentadienide (PCC) were studied by X-ray diffraction to examine the effects of different solvents on supramolecular isomerism of the PCC-ligand. While alcohols yield supramolecular isomers of [Ag(PCC)] without coordination of solvent molecules, less polar solvents show coordinate binding. The influence of solvent polarity can be observed by a gradual change in the lattice structure featuring distinct motifs. |
| Databáze: | OpenAIRE |
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