Ti-superoxide catalyzed oxidative amidation of aldehydes with saccharin as nitrogen source: synthesis of primary amides

Autor:	Gurunath Suryavanshi, A. Sudalai, Kishor D. Mane, Rohit B. Kamble, Bapurao D. Rupanawar, Pranjal Korekar
Rok vydání:	2019
Předmět:	chemistry.chemical_compound Primary (chemistry) chemistry Superoxide General Chemical Engineering Amine gas treating General Chemistry Oxidative phosphorylation Nitrogen source Combinatorial chemistry Saccharin psychological phenomena and processes Catalysis
Zdroj:	RSC advances. 10(2)
ISSN:	2046-2069
Popis:	A new heterogeneous catalytic system (Ti-superoxide/saccharin/TBHP) has been developed that efficiently catalyzes oxidative amidation of aldehydes to produce various primary amides. The protocol employs saccharin as amine source and was found to tolerate a wide range of substrates with different functional groups. Moderate to excellent yields, catalyst reusability and operational simplicity are the main highlights. A possible mechanism and the role of the catalyst in oxidative amidation have also been discussed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1423571aefda5245254ed9c14d2cd9e6 https://pubmed.ncbi.nlm.nih.gov/35494431 Zobrazit plný text záznamu