Non-peripheral tetra methoxylated pyrazoline bearing Co-II, Cu-II and (MnCl)-Cl-III phthalocyanines: Syntheses, electrochemistry and spectroelectrochemistry
| Autor: | Halise Yalazan, Halit Kantekin, Özlem Budak, Atıf Koca |
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| Přispěvatelé: | Yalazan H., KANTEKİN H., BUDAK Ö., KOCA A. |
| Jazyk: | angličtina |
| Rok vydání: | 2022 |
| Předmět: |
GRAPHENE
History Polymers and Plastics Phthalocyanines Kimya (çeşitli) Temel Bilimler (SCI) SUBSTITUTED COBALT Biochemistry Organik Kimya Pyrazoline Industrial and Manufacturing Engineering Kimya Inorganic Chemistry KİMYA İNORGANİK VE NÜKLEER CHEMISTRY Biyokimya KİMYA ORGANİK Syntheses Materials Chemistry Electrochemistry Biyoinorganik Kimya İnorganik Kimya Physical and Theoretical Chemistry Business and International Management CHEMISTRY INORGANIC & NUCLEAR Spectroelectrochemistry Bioinorganic Chemistry COMPOSITE MANGANESE PHTHALOCYANINE Temel Bilimler IRON Organic Chemistry SENSOR CHEMISTRY ORGANIC General Chemistry Genel Kimya METALLOPHTHALOCYANINES Fizik Bilimleri Chemistry (miscellaneous) Natural Sciences (SCI) Physical Sciences COMPLEXES Natural Sciences METAL-FREE BEHAVIOR |
| Popis: | The novel and highly soluble cobalt(II), copper(II) and manganese(III) phthalocyanines ((Pc-Co, Pc-Cu, and Pc-Mn) bearing 3-(5-(3,5-dimethoxyphenyl)-1-phenyl-4,5-dihydro-1H-pyrazol-3-yl)phenol have been synthesized and characterized by FT-IR, NMR, UV-Vis and mass spectroscopic methods. Additionally, electrochemical and spectroelectrochemical properties of these phthalocyanine compounds were investigated. Due to the redox inactivity of the Cu2+ central cation of (Pc-Cu), Pc based reductions and oxidation processes are recorded. [(CoPc2-)-Pc-II]/[(CoPc2-)-Pc-I](1-) and [(CoPc2-)-Pc-II]/[(CoPc2-)-Pc-III](1+) couples for the central metal redox reactions, and [(CoPc2-)-Pc-I](1-)/[(CoPc3-)-Pc-I](2-), [(CoPc3-)-Pc-I](2-)/[(CoPc4-)-Pc-I](3-) and [(CoPc2-)-Pc-III](1+)/[(CoPc1-)-Pc-III](2+) couples for the Pc based reduction and oxidation are observed respectively with (Pc-Co). Like (Pc-Co), (Pc-Mn) also illustrated metal-based reduction processes, [Cl1--(MnPc2-)-Pc-III]/[Cl1--(MnPc2-)-Pc-II](1-) and [Cl1--(MnPc2-)-Pc-II](1-)/[Cl1--(MnPc2-)-Pc-I](2-) in addition to the Pc based [Cl1--(MnPc2-)-Pc-I](2-)/[Cl1--(MnPc3-)-Pc-I](3-), [Cl1--(MnPc3-)-Pc-I](3-) /[Cl1--(MnPc4-)-Pc-I](4-) and [Cl1--(MnPc2-)-Pc-III]/[Cl1--(MnPc1-)-Pc-III](1+) redox couples were also recorded. These redox mechanisms were supported with the characteristic spectral changes observed during the in-situ spectroelectrochemical measurements. Especially metal-based electron transfer changes caused distinct spectral and color changes, which are the desired properties of the complexes for the possible opto-electrochemical applications. (C) 2022 Elsevier B.V. All rights reserved. |
| Databáze: | OpenAIRE |
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