Hydro/ Solvothermal Synthesis and Crystal Structure of New Ni(II) Coordination Polymer Containing Pamoic Acid and Ethylenediamine Mixed Ligands : {[Ni(µ-pam)(en)2]·H2O}n
| Autor: | Yasemin Tümer, Onur Şahin |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Engineering
Chemical Pamoic acid Coordination polymer Hydrogen bond Inorganic chemistry Solvothermal synthesis Mühendislik Supramolecular chemistry Infrared spectroscopy Ethylenediamine General Chemistry Crystal structure pamoic acid Hydro/ solvothermal synthesis coordination polymers pamoic acid Mühendislik Kimya lcsh:Chemistry coordination polymers chemistry.chemical_compound Crystallography Engineering lcsh:QD1-999 chemistry Hydro/ solvothermal synthesis |
| Zdroj: | Volume: 4, Issue: 3 869-876 Journal of the Turkish Chemical Society Section A: Chemistry Journal of the Turkish Chemical Society, Section A: Chemistry, Vol 4, Iss 3, Pp 869-876 (2017) |
| ISSN: | 2149-0120 |
| Popis: | The new coordination polymers arranged from flexible pamoic acid, namely {[Ni(µ-pam)(en) 2 ]·H 2 O} n ( 1 ), (H2pam= pamoic acid, en= ethylenediamine ), have been synthesized under hydro/ solvothermal conditions and characterized by elemental analysis, simultaneous TG, DTA techniques, IR spectroscopy , and X-ray crystallography. X-ray single crystal structure analysis of 1 shows that t he Ni(II) ions are bridged by pamoic acid ligands to generate 1dimensional (1D) coordination polymer running parallel to the direction, with the Ni∙∙∙Ni separation is 14.057 A. Adjacent 1D chains are connected by N-H···O and O-H···O hydrogen bonds to establishing 3 dimensional (3D) supramolecular network. An infinite 3D supramolecular network in 1 |
| Databáze: | OpenAIRE |
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