2-Chloro-3, 5-Dinitropyridine as a new ?-electron acceptor

Autor:	Y. M. Issa, H. B. Hassib
Rok vydání:	1993
Předmět:	2-CHLORO 3 5^DINITROPYRIDINE ELECTRON ACCEPTOR chemistry.chemical_classification Engineering Chemical chemistry Applied Mathematics General Mathematics 2-CHLORO-3 5^DINITROPYRIDINE K-ELECTRON Electron acceptor Photochemistry Mühendislik Kimya
Zdroj:	Volume: 39, Issue Communications Faculty of Sciences University of Ankara Series B Chemistry and Chemical Engineering
ISSN:	1303-6017 2687-4806
DOI:	10.1501/commub_0000000420
Popis:	3- Chloro-3,5-dinitropyridine was used as efficient 77-electron acceptor in the preparation of charge transfer (CT) complexes with aniline and its derivatives acting as donors. The type of interaction and structure of the formed complexes were studied using IR and electronic ab- sorption spectral studies. The primary bonding functioning in ali complexes formed is of the TC-7T* type. Secondary interactions such as n-n* and hydrogen bonding were also operative within the molecular complexes formed depending on the nature of the donor used.The electron affinity (EA) of the acceptor was calculated from electronic absorption spectral studies.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::13df600bb2a76be101a7006f87a02e87 https://doi.org/10.1501/commub_0000000420 Zobrazit plný text záznamu