Ultrahigh efficient laser desorption ionization of saccharides by Ti-based metal-organic frameworks nanosheets
| Autor: | Wenbin Shang, Yu-Jie Chang, Xizhong Yu, Zhi-Yuan Gu, Shi-Shu Yang, Hao Zhang |
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| Rok vydání: | 2018 |
| Předmět: |
Band gap
Carbohydrates 02 engineering and technology 010402 general chemistry 01 natural sciences Biochemistry Analytical Chemistry Nanomaterials law.invention Matrix (mathematics) law Ionization Environmental Chemistry Humans Particle Size Spectroscopy Metal-Organic Frameworks Titanium Range (particle radiation) Chemistry Lasers 021001 nanoscience & nanotechnology Laser Small molecule 0104 chemical sciences Nanostructures Glucose Chemical engineering Metal-organic framework 0210 nano-technology |
| Zdroj: | Analytica chimica acta. 1032 |
| ISSN: | 1873-4324 |
| Popis: | We proposed some exfoliated Ti-based metal-organic frameworks (MOFs) nanosheets as matrices with ultrahigh ionization efficiency, free matrix background, significant dispersibility and acidic resistance. Combining the features between MOFs and 2-D nanomaterials, the NTU-9 nanosheets matrix also demonstrated suitable band gap energy and superior photoabsorption properties, much better than other representative MOFs. A wide range of small molecules that involving low mass region were also analyzed with NTU-9 nanosheets as the matrices in both positive-ion and negative-ion reflector modes. The ultra-efficient NTU-9 nanosheets matrix was successfully applied to serum for quantitative determination of glucose as a clinical diagnosis indicator of diabetes mellitus. |
| Databáze: | OpenAIRE |
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