Highly efficient two-step synthesis of C-sp3-centered geminal diiodides

Autor: Jean-Manuel Cloarec, André B. Charette
Rok vydání: 2004
Předmět:
Zdroj: Organic letters. 6(25)
ISSN: 1523-7060
Popis: [reaction: see text] Trisubstituted gem-diiodoalkenes of functionalized chains are efficiently reduced to the corresponding terminal geminal diiodides in high yields upon treatment with the diazene precursor, diethyl 4-(hydrazinosulfonyl)-benzyl phosphonate.
Databáze: OpenAIRE