Ultrasound assisted oxidative desulfurization of model diesel fuel
| Autor: | Dunja Margeta, Katica Sertić-Bionda, Lucija Foglar |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
Acoustics and Ultrasonics
Waste management Batch reactor Inorganic chemistry chemistry.chemical_element Ultrasound assisted oxidative desulfurization Dibenzothiophene Diesel fuel ulfur removal N N-dimethylformamide 02 engineering and technology 021001 nanoscience & nanotechnology Sulfur Catalysis Flue-gas desulfurization chemistry.chemical_compound 020401 chemical engineering chemistry Thiophene 0204 chemical engineering 0210 nano-technology Hydrodesulfurization |
| Zdroj: | Applied Acoustics. 103:202-206 |
| ISSN: | 0003-682X |
| DOI: | 10.1016/j.apacoust.2015.07.004 |
| Popis: | Very stringent environmental regulations have limited the level of sulfur in diesel, therefore deep desulfurization of fuels is required. For that purpose, the frequently used industrial process is hydrodesulfurization (HDS) which enables effective elimination of sulfur compounds such as mercaptanes, thiols, sulfides, disulfides from diesel oil, but removal of thiophene sulfur compounds (benzothiophene, dibenzothiophene, 4,6 dimethyldibenzothiophene) is insufficient. Ultrasound assisted oxidative desulfurization (UAOD) as one of several new technologies enables performance under mild conditions without use of explosive hydrogen. A higher reactivity of thiophene sulfur compounds during UAOD also provides conversion into highly polar sulfoxides and sulfones that are easily removed by adsorption or extraction. Nowadays, different catalyst/oxidants systems are being studied to improve oxidation reaction efficiency and enhance the mass transfer in the interfacial region. In this paper, the effect of reaction temperature (40–70 °C) and oxidation time (5–150 min) for UAOD of model diesel fuel with a catalyst/oxidants system (acetic acid/hydrogen peroxide) was investigated in a 70 ml batch reactor. Furthermore, the effects of different initial concentrations of dibenzothiophene (DBT) and of ultrasound amplitude were additionally examined to achieve efficient sulfur removal. The obtained results indicated that temperature and US amplitude of 70 °C and 80% respectively were efficient for conversion of DBT (sulfur concentration up to 3976.86 ppm). The results indicate a rise in the yield of sulfones at higher temperatures and subsequent extraction with N , N -dimethylformamide conducted after the process of oxidation at different solvent/oil ratio revealed sulfur removal efficiency of 98.35%. |
| Databáze: | OpenAIRE |
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