Amide-directed alkenylation of sp2 C-H bonds catalyzed by a cationic Rh(I)/BIPHEP complex under mild conditions: dramatic rate acceleration by a 1-pyrrolidinecarbonyl group

Autor:	Ken Tanaka, Masao Hirano, Yousuke Otake, Yu Shibata
Jazyk:	angličtina
Rok vydání:	2015
Předmět:	Reaction conditions Chemistry Stereochemistry Organic Chemistry Cationic polymerization Regioselectivity chemistry.chemical_element Biochemistry Medicinal chemistry Catalysis Rhodium chemistry.chemical_compound Group (periodic table) Amide Physical and Theoretical Chemistry
Zdroj:	Organic Letters. 11(No. 3):689-692
ISSN:	1523-7060
Popis:	A cationic rhodium(I)/BIPHEP complex catalyzes amide-directed regioselective alkenylations of olefinic or aromatic sp(2) C-H bonds in good yields under mild reaction conditions. The use of a 1-pyrrolidinecarbonyl group as a directing group dramatically accelerates the reaction.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::11fdc400cf207edb62298baa007373d3 http://t2r2.star.titech.ac.jp/cgi-bin/publicationinfo.cgi?q_publication_content_number=CTT100692622 Zobrazit plný text záznamu