tert-Butyl nitrite mediated nitrogen transfer reactions: synthesis of benzotriazoles and azides at room temperature
| Autor: | Sadaf Azeez, Shahulhameed Sabiah, Popuri Sureshbabu, Jeyakumar Kandasamy, Priyanka Chaudhary |
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| Rok vydání: | 2018 |
| Předmět: |
Tert butyl
Sulfonyl chemistry.chemical_classification 010405 organic chemistry Chemistry Organic Chemistry chemistry.chemical_element 010402 general chemistry 01 natural sciences Biochemistry Nitrogen 0104 chemical sciences Catalysis chemistry.chemical_compound Polymer chemistry Physical and Theoretical Chemistry Nitrite |
| Zdroj: | Organic & Biomolecular Chemistry. 16:8280-8285 |
| ISSN: | 1477-0539 1477-0520 |
| DOI: | 10.1039/c8ob01950a |
| Popis: | A conversion of o-phenylenediamines into benzotriazoles was achieved at room temperature using tert-butyl nitrite. The optimized conditions are also well suited for the transformation of sulfonyl and acyl hydrazines into corresponding azides. This protocol does not require any catalyst or acidic medium. The desired products were obtained in excellent yields in a short span of time. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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