The thermal desulfination of allylic sulfonyl halides

Autor:	Malcolm D. King, Rodney E. Sue, David J. Young, Rodney H. White
Předmět:	Sulfonyl chemistry.chemical_classification Allylic rearrangement Bromine Chemistry Organic Chemistry Allyl compound Halide chemistry.chemical_element Biochemistry Medicinal chemistry chemistry.chemical_compound Stereospecificity Bromide Yield (chemistry) Drug Discovery Organic chemistry
Zdroj:	ResearcherID
Popis:	Allylic sulfonyl halides can be generated by halogenolysis of the corresponding triorganotin sulfinates. Allylic sulfonyl bromides and iodides undergo a first order, thermal desulfination with allylic rearrangement to yield the corresponding allylic halides. The desulfination of a cyclic allylic sulfonyl bromide is stereospecific, proceeding with γ-syn bromine migration.
Databáze:	OpenAIRE
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