Maxwell Stress to Explain the Mechanism for the Anisotropic Expansion in Lithiated Silicon Nanowires
| Autor: | Boone, Donald |
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| Rok vydání: | 2017 |
| Předmět: | |
| DOI: | 10.6084/m9.figshare.5203690 |
| Popis: | This computational research study attempts to explain the process that leads to volume expansion during insertion of lithium ions into a silicon nanowire. During lithiation, electrons flow through the nanowire in the opposing direction of lithium ions insertion. This causes an applied electromagnetic field which is described as being a quantum mechanical version of photon density wave theory. A series of events are calculated as the individual electrons and photons travels through the lithiated silicon nanowire. The hypothesis that will be presented employs the Maxwell stress tensor to calculate the refractive indices in three orthogonal directions during lithiation. The quantum harmonic oscillator and the electromagnetic intensity will be utilized in this presentation to calculate the energy of electrons and optical amplification of the electromagnetic field respectively. The main focus of this research study will use electron scattering theory, spontaneous and stimulated emission theory to model the breaking of cohesion bonds between silicon atoms that ultimately leads to excessive volume expansion that is witnessed during the lithiation process in Si nanowires. |
| Databáze: | OpenAIRE |
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