Crystal structures of (N-methyl-N-phenylamino)(N-methyl-N-phenylcarbamoyl)sulfide and the corresponding disulfane
| Autor: | Matthew J. Henley, Victor G. Young, Alayne L. Schroll, George Barany |
|---|---|
| Jazyk: | angličtina |
| Rok vydání: | 2015 |
| Předmět: |
Sulfenyl chloride
crystal structure Sulfide organosulfur chemistry Nanotechnology Crystal structure Dihedral angle Chloride Medicinal chemistry Research Communications chemistry.chemical_compound disulfane medicine General Materials Science heterocyclic compounds chemistry.chemical_classification sulfide Crystallography Hydrogen bond General Chemistry Condensed Matter Physics hydrogen bonding Graph chemistry QD901-999 medicine.drug |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 11, Pp 1371-1374 (2015) Acta Crystallographica Section E: Crystallographic Communications |
| ISSN: | 2056-9890 |
| Popis: | (N-Methyl-N-phenylcarbamoyl)(N-methyl-N-phenylamino)sulfide and the corresponding disulfane are stable derivatives of (chlorocarbonyl)sulfenyl chloride and (chlorocarbonyl)disulfanyl chloride, respectively. The title compounds, (N-methyl-N-phenylamino)(N-methyl-N-phenylcarbamoyl)sulfide, C15H16N2OS, (I), and (N-methyl-N-phenylamino)(N-methyl-N-phenylcarbamoyl)disulfane, C15H16N2OS2, (II), are stable derivatives of (chlorocarbonyl)sulfenyl chloride and (chlorocarbonyl)disulfanyl chloride, respectively. The torsion angle about the S—S bond in (II) is −92.62 (6)°, which is close to the theoretical value of 90°. In the crystal of (II), non-classical intermolecular C—H⋯O hydrogen bonds form centrosymmetric cyclic dimers [graph set R 2 2(10)], while inter-dimer C—H⋯S interactions generate chains extending along the b axis. |
| Databáze: | OpenAIRE |
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