Electrochemically Controlled Hydrogen Bonding. Electrolyte Effects in an Oxidation-Based Arylurea−Amide System

Autor:	Yu Ge, Jessica E. Woods, Diane K. Smith
Rok vydání:	2008
Předmět:	chemistry.chemical_compound Colloid and Surface Chemistry chemistry Hydrogen bond Amide Inorganic chemistry Urea macromolecular substances General Chemistry Electrolyte Electrolyte anion Biochemistry Catalysis
Zdroj:	Journal of the American Chemical Society. 130:10070-10071
ISSN:	1520-5126 0002-7863
DOI:	10.1021/ja803453e
Popis:	Oxidation of a dimethylaminophenyl-substituted urea leads to a > 2000-fold increase in binding strength between the urea and a diamide guest in 0.1 M NBu4B(C6F5)4/CH2Cl2. The strength of this interaction is obscured when NBu4ClO4 or NBu4PF6 is used as the electrolyte due to competition between the neutral guest and the electrolyte anion for H-bonding to the urea cation.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1100523bb3417704cfa1aa54f8b6a470 https://doi.org/10.1021/ja803453e Zobrazit plný text záznamu