New Twists and Turns for Actinide Chemistry: Organometallic Infinite Coordination Polymers of Thorium Diazide
| Autor: | Brian L. Scott, Lani A. Seaman, Marisa J. Monreal, Jaqueline L. Kiplinger, David E. Morris, George S. Goff, Ryszard Michalczyk |
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| Rok vydání: | 2016 |
| Předmět: |
chemistry.chemical_classification
Steric effects Actinide chemistry 010405 organic chemistry Ligand Inorganic chemistry Thorium chemistry.chemical_element General Medicine General Chemistry Polymer 010402 general chemistry 01 natural sciences Catalysis 0104 chemical sciences chemistry.chemical_compound chemistry Polymer chemistry Azide Metallocene |
| Zdroj: | Angewandte Chemie International Edition. 55:3631-3636 |
| ISSN: | 1433-7851 |
| DOI: | 10.1002/anie.201510851 |
| Popis: | Two organometallic 1D infinite coordination polymers and two organometallic monometallic complexes of thorium diazide have been synthesized and characterized. Steric control of these self-assembled arrays, which are dense in thorium and nitrogen, has also been demonstrated: infinite chains can be circumvented by using steric bulk either at the metallocene or with a donor ligand in the wedge. |
| Databáze: | OpenAIRE |
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