Intramolecular Interactions of a Phenyl/Perfluorophenyl Pair in the Formation of Supramolecular Nanofibers and Hydrogels

Autor:	Hsin-Chieh Lin, Yu Chun Lin, Shu-Min Hsu, Jui Wen Chang, Yu Hao Liu
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Phenylalanine Molecular Sequence Data Nanofibers technology industry and agriculture Supramolecular chemistry Hydrogels macromolecular substances General Chemistry General Medicine complex mixtures Catalysis Fluorobenzenes chemistry Intramolecular force Nanofiber Polymer chemistry Self-healing hydrogels Side chain Humans Non-covalent interactions Moiety Amino Acid Sequence Self-assembly Peptides
Zdroj:	Angewandte Chemie. 126:1952-1958
ISSN:	0044-8249
DOI:	10.1002/ange.201307500
Popis:	A new system for the incorporation of a phenyl/perfluorophenyl pair in the structure of a peptide hydrogelator was developed. The strategy is based on the idea that the integration of an end-capped perfluorophenyl group and a phenylalanine with a phenyl moiety in the side chain forms an intramolecular phenyl/perfluorophenyl pair, which can be used to promote the formation of the supramolecular nanofibers and hydrogels. This work illustrates the importance of structure-hydrogelation relationship and provides new insights into the design of self-assembly nanobiomaterials.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::109ab2c09d3c2b536ad8daf712b6baa1 https://doi.org/10.1002/ange.201307500 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
Nepřihlášeným uživatelům se plný text nezobrazuje	K zobrazení výsledku je třeba se přihlásit.