Photocatalytic Aminodecarboxylation of Carboxylic Acids
| Autor: | Richard Welter, Kaitie C. Cartwright, Jon A. Tunge, Theresa M. Locascio, Simon B. Lang |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
chemistry.chemical_classification
010405 organic chemistry Organic Chemistry Homogeneous catalysis 010402 general chemistry 01 natural sciences Article 0104 chemical sciences chemistry.chemical_compound chemistry Electrophile Photocatalysis Organic chemistry Diazo Physical and Theoretical Chemistry Amination Alkyl |
| Zdroj: | European journal of organic chemistry. 2016(20) |
| ISSN: | 1434-193X |
| Popis: | Aminodecarboxylation of unactivated alkyl carboxylic acids has been accomplished utilizing an organic photocatalyst. This operationally simple reaction utilizes readily available carboxylic acids to chemoselectively generate reactive alkyl intermediates that are not accessible via conventional two-electron pathways. The organic radical intermediates are efficiently trapped with electrophilic diazo compounds to provide aminated alkanes. |
| Databáze: | OpenAIRE |
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