Archimedean Tilings and Hierarchical Lamellar Morphology Formed by Semicrystalline Miktoarm Star Terpolymer Thin Films
| Autor: | Guillaume Fleury, Mireille Maret, Giuseppe Portale, Muhammad Mumtaz, Ségolène Antoine, Karim Aissou, Wonsang Kwon, Georges Hadziioannou |
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| Přispěvatelé: | Laboratoire de Chimie des Polymères Organiques (LCPO), Centre National de la Recherche Scientifique (CNRS)-Institut Polytechnique de Bordeaux-Ecole Nationale Supérieure de Chimie, de Biologie et de Physique (ENSCBP)-Université de Bordeaux (UB)-Institut de Chimie du CNRS (INC), Team 4 LCPO : Polymer Materials for Electronic, Energy, Information and Communication Technologies, Centre National de la Recherche Scientifique (CNRS)-Institut Polytechnique de Bordeaux-Ecole Nationale Supérieure de Chimie, de Biologie et de Physique (ENSCBP)-Université de Bordeaux (UB)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Institut Polytechnique de Bordeaux-Ecole Nationale Supérieure de Chimie, de Biologie et de Physique (ENSCBP)-Université de Bordeaux (UB)-Institut de Chimie du CNRS (INC), CNRS IPB, Lab Sci & Ingn Mat & Proc, Univ Groningen, Zernike Inst Adv Mat, Macromol Chem & New Polym Mat, University of Groningen [Groningen], Macromolecular Chemistry & New Polymeric Materials, Université de Bordeaux (UB)-Ecole Nationale Supérieure de Chimie, de Biologie et de Physique (ENSCBP)-Institut Polytechnique de Bordeaux-Centre National de la Recherche Scientifique (CNRS), École des Ponts ParisTech (ENPC), Science et Ingénierie des Matériaux et Procédés [2016-2019] (SIMaP [2016-2019]), Institut polytechnique de Grenoble - Grenoble Institute of Technology [2007-2019] (Grenoble INP [2007-2019])-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019]), NWO DUBBLE CRG (ESRF, Netherlands Org Sci Res), European Synchrotron Radiation Facility (ESRF) |
| Jazyk: | angličtina |
| Rok vydání: | 2016 |
| Předmět: |
Morphology (linguistics)
Materials science General Physics and Astronomy 02 engineering and technology Star (graph theory) 010402 general chemistry 01 natural sciences Crystallinity topographical substrate TOMOGRAPHY Polymer chemistry directed self-assembly Copolymer General Materials Science Lamellar structure Thin film HETEROARM General Engineering [CHIM.MATE]Chemical Sciences/Material chemistry SHAPED TERPOLYMERS COPOLYMER 021001 nanoscience & nanotechnology 0104 chemical sciences SQUARE Crystallography [CHIM.POLY]Chemical Sciences/Polymers Volume fraction 3-miktoarm star terpolymer POLYSTYRENE Grazing-incidence small-angle scattering Archimedean tiling hierarchical lamellar pattern POLYMERS 0210 nano-technology |
| Zdroj: | ACS Nano ACS Nano, American Chemical Society, 2016, 10 (4), pp.4055-4061. ⟨10.1021/acsnano.5b06728⟩ Acs Nano, 10(4), 4055-4061. AMER CHEMICAL SOC |
| ISSN: | 1936-0851 |
| DOI: | 10.1021/acsnano.5b06728⟩ |
| Popis: | International audience; 3-Miktoarm star terpolymer architecture provides a window of opportunity in the design of complex "three-colored" patterns at the nanometer scale. Here, the directed self-assembly (DSA) of 3-miktoarm star terpolymer (poly(1, 1-dimethyl silacydobutane)-arm-polystyrene-armpoly(D,L-lactide acid)) (PDMSB-arm-PS-arm-PLA, noted hereafter 3 mu-DSL) into a hierarchical lamellar morphology is described. Excellent orientational order has been achieved by templating the asymmetric hierarchical lamellar morphology with topographical substrates. Increasing the PLA volume fraction leads to the formation of a hexagonal [6.6.6] Archimedean tiling which coexists with a metastable square symmetry [4.8.8] tiling stabilized by the step between terraces. Stability of the [6.6.6] tiling over the [4.8.8] one is also demonstrated with GISAXS measurements. |
| Databáze: | OpenAIRE |
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