ChemInform Abstract: Alkylation and Aldol Reactions of Acyl Derivatives of N-1-(1′-Naphthyl)ethyl-O-tert-butylhydroxylamine: Asymmetric Synthesis of α-Alkoxy-, α-Substituted-β-alkoxy- and α,β-Dialkoxyaldehydes

Autor: Christopher J. Goodwin, Edward D. Savory, Paul M. Roberts, Andrew Smith, Ai M. Flechter, David Hepworth, Stephen G. Davies, Alexander N. Chernega, R. Shyam Prasad, James E. Thomson
Rok vydání: 2010
Předmět:
Zdroj: ChemInform. 41
ISSN: 0931-7597
DOI: 10.1002/chin.201039053
Popis: Alternatively, the chiral auxiliary promotes aldol reactions to give syn-aldol products such as (XIII), (XVI), or (XX) with good diastereocontrol over both newly generated stereogenic centers.
Databáze: OpenAIRE