Synthesis of Nanometer-Sized Cylinder-Like Structures from a 1,3,5-Triphenylbenzene-Bridged Tris-NHC Ligand and AgI, AuI, and CuI

Autor:	Alexander Hepp, Eduardo Peris, Florian Roelfes, Narayan Sinha, F. Ekkehardt Hahn, Carmen Mejuto
Rok vydání:	2014
Předmět:	Inorganic Chemistry Tris Crystallography Transmetalation chemistry.chemical_compound chemistry Ligand Yield (chemistry) Organic Chemistry Nanometre Physical and Theoretical Chemistry
Zdroj:	Organometallics. 33:6898-6904
ISSN:	1520-6041 0276-7333
DOI:	10.1021/om500973b
Popis:	The metal-controlled self-assembly of nanometer-sized trinuclear cylinder-like assemblies is described. The 1,3,5-triphenylbenzene-derived trisimidazolium salt [1](PF6)3 reacts with 1.5 equiv of Ag2O to yield the trinuclear AgI hexacarbene complex [2](PF6)3, where three AgI ions are sandwiched in between two C3-symmetric tris-NHC ligands. Transmetalation of [2](PF6)3 with 3 equiv of [AuCl(SMe2)] or CuI yields the trinuclear AuI hexacarbene complex [3](PF6)3 or the trinuclear CuI hexacarbene complex [4](PF6)3, respectively, with retention of the metallosupramolecular structure. The 1,3,5-triphenylbenzene ligand in the gold complex adopts a nonplanar geometry to allow π interactions between the central phenyl rings.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1029b4ef1df6a03d80a25efe20d35588 https://doi.org/10.1021/om500973b Zobrazit plný text záznamu