Synthesis of Dendrimers with a Bidentate Phosphine Core Ligand Having Carboxy Groups at the Peripheral Layer and Their Application to Aqueous Media Cross-Coupling Reactions
| Autor: | Hatsuhiko Hattori, Ken-ichi Fujita |
|---|---|
| Rok vydání: | 2016 |
| Předmět: |
inorganic chemicals
Dendrimers Denticity Phosphines Core (manufacturing) Ligands 010402 general chemistry Photochemistry 01 natural sciences Catalysis Coupling reaction chemistry.chemical_compound Dendrimer Drug Discovery Polymer chemistry Organometallic Compounds Molecular Structure 010405 organic chemistry Chemistry Ligand Water General Chemistry General Medicine 0104 chemical sciences Solubility Layer (electronics) Palladium Phosphine |
| Zdroj: | CHEMICAL & PHARMACEUTICAL BULLETIN. 64:1067-1072 |
| ISSN: | 1347-5223 0009-2363 |
| Popis: | We prepared a series of dendrimers with a bidentate phosphine core ligand having carboxy groups at the peripheral layer. By employing the corresponding water-soluble dendritic phosphine-palladium complex as a catalyst, the aqueous media Suzuki-Miyaura reaction and Tsuji-Trost reaction proceeded to provide the corresponding cross-coupling product. |
| Databáze: | OpenAIRE |
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