Highly Efficient Electrocatalytic Carboxylation of 1-Phenylethyl Chloride at Cu Foam Cathode
| Autor: | Qi-Long Sun, La-Xia Wu, Huan Wang, Ye-Bin Guan, Man-Ping Yang, Ying-Guo Zhao, Lu Jiaxing |
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| Jazyk: | angličtina |
| Rok vydání: | 2018 |
| Předmět: |
Materials science
Galvanic anode Inorganic chemistry 02 engineering and technology 010402 general chemistry lcsh:Chemical technology 01 natural sciences Chloride Catalysis benzyl chlorides law.invention lcsh:Chemistry carboxylation chemistry.chemical_compound law medicine lcsh:TP1-1185 Physical and Theoretical Chemistry carbon dioxide electrocatalytic 021001 nanoscience & nanotechnology Cathode 0104 chemical sciences Solvent Benzyl chloride Carboxylation chemistry lcsh:QD1-999 Yield (chemistry) Cu foam 0210 nano-technology medicine.drug |
| Zdroj: | Catalysts Volume 8 Issue 7 Catalysts, Vol 8, Iss 7, p 273 (2018) |
| ISSN: | 2073-4344 |
| DOI: | 10.3390/catal8070273 |
| Popis: | A simple and efficient electrocatalytic carboxylation of benzyl chloride with CO2 is described. The reaction operates under 1 atm CO2 and room temperature in an undivided cell with Cu foam cathode and Mg sacrificial anode without any additional catalyst. For the model compound 1-phenylethyl chloride, the influence of cathode material, solvent, charge, current density and temperature were investigated. Under optimized conditions, 99% yield of 2-phenylpropionic acid could be obtained. Moreover, reasonable yields were also achieved with other benzyl chlorides. |
| Databáze: | OpenAIRE |
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