Analysis of electrocatalytic metal-organic frameworks
| Autor: | Ashleigh T. Castner, Timofey Liseev, Anna M. Beiler, Ben A. Johnson, Sascha Ott, Brian D. McCarthy |
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| Jazyk: | angličtina |
| Předmět: |
010405 organic chemistry
Chemistry Nanotechnology Solid material 010402 general chemistry Solar fuel Electrochemistry Electrocatalyst 7. Clean energy 01 natural sciences Article 0104 chemical sciences Characterization (materials science) Inorganic Chemistry 13. Climate action Homogeneous Materials Chemistry Metal-organic framework Physical and Theoretical Chemistry |
| Zdroj: | Coord Chem Rev Coordination Chemistry Reviews |
| ISSN: | 0010-8545 |
| DOI: | 10.1016/j.ccr.2019.213137 |
| Popis: | The electrochemical analysis of molecular catalysts for the conversion of bulk feedstocks into energy-rich clean fuels has seen dramatic advances in the last decade. More recently, increased attention has focused on the characterization of metal-organic frameworks (MOFs) containing well-defined redox and catalytically active sites, with the overall goal to develop structurally stable materials that are industrially relevant for large-scale solar fuel syntheses. Successful electrochemical analysis of such materials draws heavily on well-established homogeneous techniques, yet the nature of solid materials presents additional challenges. In this tutorial-style review, we cover the basics of electrochemical analysis of electroactive MOFs, including considerations of bulk stability, methods of attaching MOFs to electrodes, interpreting fundamental electrochemical data, and finally electrocatalytic kinetic characterization. We conclude with a perspective of some of the prospects and challenges in the field of electrocatalytic MOFs. |
| Databáze: | OpenAIRE |
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