Chitosan adsorption on nanofibrillated cellulose with different aldehyde content and interaction with phosphate buffered saline
| Autor: | Sedat Ondaral, Orçun Çağlar Kurtuluş, E. Asikuzun, Elif Çelik, İsmail Yakın |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Polymers and Plastics
Surface Properties Nanofibers macromolecular substances 02 engineering and technology 010402 general chemistry 01 natural sciences Aldehyde Chitosan chemistry.chemical_compound Acetic acid Crystallinity Adsorption Materials Chemistry medicine Cellulose chemistry.chemical_classification Aldehydes Organic Chemistry technology industry and agriculture Quartz crystal microbalance equipment and supplies 021001 nanoscience & nanotechnology 0104 chemical sciences Molecular Weight carbohydrates (lipids) chemistry Swelling medicine.symptom 0210 nano-technology Nuclear chemistry |
| Zdroj: | Carbohydrate Polymers. 186:192-199 |
| ISSN: | 0144-8617 |
| DOI: | 10.1016/j.carbpol.2017.12.028 |
| Popis: | The chitosan adsorption on films prepared using nanofibrillated cellulose (NFC) with different content of aldehyde group was studied by means of Quartz Crystal Microbalance with Dissipation (QCM-D). Results showed that frequency change (Δf) was higher when the chitosan adsorbed on NFC film consisting more aldehyde group indicating the higher adsorption. The (Δf) and dissipation (ΔD) factors completely changed during adsorption of chitosan pre-treated with acetic acid: Δf increased and ΔD decreased, oppositely to un-treated chitosan adsorption. After acid treatment, molecular weight and crystallinity index of chitosan decreased addition to change in chemical structure. It was found that more phosphate buffered saline (PBS), as a model liquid for wound exudate, adsorbed to acid treated chitosan-NFC film, especially to film having more aldehyde groups. Comparing with bare NFC film, chitosan-NFC films adsorbed less PBS because chitosan crosslinked the NFC network and blocked the functional groups of NFC and thus, preventing swelling film. |
| Databáze: | OpenAIRE |
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