| Autor: |
Shaoqun Zhu, Yingjie Pan, Yue Sun, Xiaoyan Hong, Xiaoyun Chen, Ying Han, Chaoguo Yan, Yaocheng Shi, Hong Hou |
| Rok vydání: |
2022 |
| Předmět: |
|
| Zdroj: |
The Journal of organic chemistry. 87(6) |
| ISSN: |
1520-6904 |
| Popis: |
A copper-catalyzed bromo-cyanomethylative cyclization of 1,6-enynes is demonstrated. The treatment of 2-bromoacetonitrile with CuI enables the alkyl radical generation and triggers the radical addition/cyclization/bromination sequence, giving various vinyl C-Br bonds containing functionalized heterocycles in good yields. |
| Databáze: |
OpenAIRE |
| Externí odkaz: |
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