α-Ketocarbenium Ions Derived from Orthoquinone-Containing Polycyclic Aromatic Compounds
| Autor: | Michinori Sumimoto, Kazuki Urakawa, Hayato Ishikawa, Masaki Matsuda, Yuta Kawabata |
|---|---|
| Rok vydání: | 2018 |
| Předmět: |
Absorption spectroscopy
Fluorosulfonic acid Organic Chemistry Sulfuric acid 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Biochemistry 0104 chemical sciences Ion chemistry.chemical_compound chemistry Polymer chemistry Aromatic moiety Physical and Theoretical Chemistry Absorption (chemistry) 0210 nano-technology Brønsted–Lowry acid–base theory |
| Zdroj: | Organic Letters. 20:2534-2537 |
| ISSN: | 1523-7052 1523-7060 |
| DOI: | 10.1021/acs.orglett.8b00682 |
| Popis: | α-Ketocarbenium ions derived from synthesized orthoquinone-containing polycyclic aromatic compounds were generated in the presence of Brønsted acids such as sulfuric acid, trifluoromethanesulfonic acid, and fluorosulfonic acid. The prepared α-ketocarbenium ions were stabilized by conjugation of the aromatic moiety. In addition, unique absorption properties of the α-ketocarbenium ions were observed and identified on the basis of the calculated absorption spectra. It was suggested that the zigzag-shaped architecture stabilizes the newly discovered α-ketocarbenium ions derived from orthoquinone-containing polycyclic aromatic compounds. |
| Databáze: | OpenAIRE |
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