Iridium-Catalyzed Dynamic Kinetic Isomerization: Expedient Synthesis of Carbohydrates from Achmatowicz Rearrangement Products

Autor:	Weiping Tang, Hao-Yuan Wang, Ka Yang, Scott R. Bennett, Sheng-rong Guo
Rok vydání:	2015
Předmět:	Chemistry Carbohydrates chemistry.chemical_element General Chemistry General Medicine Iridium Redox Catalysis De novo synthesis Isomerism Organic chemistry Stereoselectivity Enantiomer Isomerization
Zdroj:	Angewandte Chemie. 127:8880-8883
ISSN:	0044-8249
DOI:	10.1002/ange.201503151
Popis:	A highly stereoselective dynamic kinetic isomerization of Achmatowicz rearrangement products was discovered. This new internal redox isomerization provided ready access to key intermediates for the enantio- and diastereoselective synthesis of a series of naturally occurring sugars. The nature of the de novo synthesis also enables the preparation of both enantiomers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0ed0622c648eaf4f99b0ee1e5f13f555 https://doi.org/10.1002/ange.201503151 Zobrazit plný text záznamu Plný text ve formátu PDF