Hypervalent Iodine Mediated Synthesis of C-2 Deoxy Glycosides and Amino Acid Glycoconjugates

Autor:	Maidul Islam, Srinivas Hotha, Shyamapada Nandi, Nishanth D. Tirukoti
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Magnetic Resonance Spectroscopy Chemistry Stereochemistry Glycoconjugate Organic Chemistry Hypervalent molecule Halogenation Glycoside chemistry.chemical_element Stereoisomerism Iodine Amino acid Organic chemistry Rhodium Glycosides Amino Acids Glycoconjugates
Zdroj:	The Journal of Organic Chemistry. 79:4470-4476
ISSN:	1520-6904 0022-3263
DOI:	10.1021/jo500465m
Popis:	A simple, efficient, and practical method for the synthesis of C-2 deoxy-2-iodo glycoconjugates in self-assembled structures was found using PhI(OCOR)2. 2-Iodo glycoserinyl esters were intramolecularly converted into 2-iodo serinyl glycosides which upon dehalogenation gave C-2 deoxy amino acid glycoconjugates.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0e9de2c6ecb3eaa2c376e5c80de7ab92 https://doi.org/10.1021/jo500465m Zobrazit plný text záznamu