Mild, Metal-Free Oxidative Ring-Expansion Approach for the Synthesis of Benzo[b]azepines

Autor:	Dariusz G. Piekarski, Sebastian Stockerl, Tobias Danelzik, Olga García Mancheño
Rok vydání:	2019
Předmět:	010405 organic chemistry Chemistry Organic Chemistry Oxidative phosphorylation 010402 general chemistry Ring (chemistry) 01 natural sciences Biochemistry Combinatorial chemistry 0104 chemical sciences Catalysis Metal free Physical and Theoretical Chemistry Structural motif
Zdroj:	Organic Letters. 21:4535-4539
ISSN:	1523-7052 1523-7060
Popis:	Benzo[ b]azepines are important structural motifs for the pharmaceutical industry. However, their syntheses are usually lengthy, involving several steps, transition-metal catalysts, and/or harsh conditions. A novel, general, mild, and metal-free oxidative ring expansion tandem reaction of hydroquinolines with TMSCHN
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0e682c42edc4bbf8b9cdcf1966ffd4d6 https://doi.org/10.1021/acs.orglett.9b01433 Zobrazit plný text záznamu