Hydrogen Peroxide Solvates of 2,4,6,8,10,12-Hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane
| Autor: | Nilanjana Chowdhury, Adam J. Matzger, Jonathan C. Bennion, Jeff W. Kampf |
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| Rok vydání: | 2016 |
| Předmět: |
010405 organic chemistry
Chemistry Inorganic chemistry Detonation General Medicine 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Oxygen balance Catalysis 0104 chemical sciences Crystallography chemistry.chemical_compound 0210 nano-technology Hydrogen peroxide Hydrate |
| Zdroj: | Angewandte Chemie International Edition. 55:13118-13121 |
| ISSN: | 1433-7851 |
| DOI: | 10.1002/anie.201607130 |
| Popis: | Two polymorphic hydrogen peroxide solvates of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20; wurtzitane is an alternative name to iceane) were obtained using hydrated α-CL-20 as a guide. These novel H2O2 solvates have high crystallographic densities (1.96 and 2.03 g cm−3, respectively), high predicted detonation velocities/pressures (with one solvate performing better than ϵ-CL-20), and a sensitivity similar to that of ϵ-CL-20. The use of hydrated materials as a guide will be important in the development of other energetic materials with hydrogen peroxide. These solvates represent an area of energetic materials that has yet to be explored. |
| Databáze: | OpenAIRE |
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