Influence of pretreatment with Fenton’s reagent on biogas production and methane yield from lignocellulosic biomass

Autor: Liliana Krzystek, Krystian Miazek, Stanisław Ledakowicz, Karina Michalska
Rok vydání: 2012
Předmět:
Zdroj: Bioresource Technology. 119:72-78
ISSN: 0960-8524
Popis: Biomass from Miscanthus giganteus , Sida hermaphrodita and Sorghum Moensch was treated with Fenton’s reagent for 2 hours under optimal conditions (pH = 3, mass ratio of [Fe 2+ ]:[H 2 O 2 ] equals 1:25 for Miscanthus and Sorghum and 1:15 for Sida ). The degrees of delignification were 30.3%, 62.3% and 48.1% for the three plant species, respectively. The volatile fatty acids concentration after chemical pretreatment was high enough for production of biogas with a high methane content. Combined chemical oxidation and enzymatic hydrolysis with cellulase and cellobiase led to glucose contents of above 4 g/L. Among the tested plants, the highest biogas production (25.2 Ndm 3 /kg TS fed) with a 75% methane content was obtained with Sorghum Moensch. The results of the three-step process of biomass degradation show the necessity of applying a chemical pretreatment such as oxidation with Fenton’s reagent. Moreover, the coagulation of residual Fe 3+ ions is not required for high biogas production.
Databáze: OpenAIRE