Reversible activation of water by an air‐ and moisture‐stable frustrated rhodium nitrogen Lewis pair
| Autor: | Fernando J. Lahoz, Pilar García-Orduña, Daniel Carmona, Joaquina Ferrer, Vincenzo Passarelli, Ricardo Rodríguez, María Carmona, Laura Cañadillas-Delgado |
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| Přispěvatelé: | Ministerio de Economía y Competitividad (España), Gobierno de Aragón, European Commission |
| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: |
H/D exchange
Electron pair 010405 organic chemistry Chemistry HO−H bond activation Organic Chemistry chemistry.chemical_element General Chemistry 010402 general chemistry Coordination modes 01 natural sciences Catalysis Frustrated Lewis pair 0104 chemical sciences Rhodium reaction mechanisms Humanities frustrated Lewis pairs |
| Zdroj: | 'Chemistry-A European Journal ', vol: 25, pages: 13665-13670 (2019) Digital.CSIC. Repositorio Institucional del CSIC instname |
| Popis: | [Cp*Rh(κN,N′,P-L)][SbF] (Cp*=CMe), bearing a guanidine-derived phosphano ligand L, behaves as a “dormant” frustrated Lewis pair and activates H and HO in a reversible manner. When DO is employed, a facile H/D exchange at the Cp* ring takes place through sequential C(sp)−H bond activation. We thank the Ministerio de Economía y Competitividad of Spain (CTQ2015‐66079‐P) and Gobierno de Aragón (Grupo Consolidado E05‐17R: Catálisis Homogénea Enantioselectiva) for financial support. M.C. acknowledges Diputación General de Aragón, CSIC and European Social Fund for a grant. R.R. acknowledges the Ministerio de Economía y Competitividad of Spain for a Ramón y Cajal (RYC‐2013‐13800) grant. P.G.‐O. acknowledges CSIC, European Social Fund and Ministerio de Economía y Competitividad of Spain for a PTA contract. |
| Databáze: | OpenAIRE |
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