Expanding the Boxmi Ligand Family: Synthesis and Application of NON and NSN Ligands

Autor: Hubert Wadepohl, David Bürgy, Yan-Kai Liu, Lutz H. Gade, Qing-Hai Deng, Bin Li, Clemens K. Blasius, Ina Michalsky, Bing-Tao Ren
Rok vydání: 2020
Předmět:
Zdroj: The Journal of organic chemistry. 85(10)
ISSN: 1520-6904
Popis: Two synthetic strategies for a new family of neutral NON ligands featuring a "bis(oxazolinylmethylidene)isobenzofuran" framework (boxman) are reported. A Pd-mediated cyclization reaction forming the isobenzofuran core constitutes the key reaction in the eight-step synthetic route to the nonbackbone-methylated target compound
Databáze: OpenAIRE