Manganese(III) acetate-mediated synthesis of biaryls under microwave irradiation

Autor:	Nezire Saygili, Hamide Findik, N. Tuna Subasi, Ayhan S. Demir
Rok vydání:	2010
Předmět:	Green chemistry Organic Chemistry chemistry.chemical_element Manganese Biochemistry Chemical synthesis chemistry.chemical_compound Acetic acid chemistry Manganese(III) acetate Yield (chemistry) Reagent Drug Discovery Thiophene Organic chemistry Nuclear chemistry
Zdroj:	Tetrahedron. 66:1308-1312
ISSN:	0040-4020
DOI:	10.1016/j.tet.2009.12.018
Popis:	Manganese(Ill) acetate (Mn(OAc)(3))-mediated synthesis of biaryls and heterobiaryls starting from arylboronic acid was developed under microwave irradiation in high yields Microwaves were also used for the synthesis of Mn(OAc)(3) from KMnO4 and acetic acid Additional irradiation of this in situ generated Mn(OAc)3 with arylboronic acids, which in turn furnished the biaryls in high yields In a one pot reaction This IS superior from the point of view of yield, short reaction time, sensitive functional group toleration, and more environmentally friendly than the reported methods with a minimum amount of benzene and thiophene as a reagent but not as a solvent (C) 2009 Elsevier Ltd All rights reserved
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0dda52cbde43c9e2ebfea24d586d5b65 https://doi.org/10.1016/j.tet.2009.12.018 Zobrazit plný text záznamu Full Text from ScienceDirect