Copper-catalyzed Hiyama cross-coupling using vinylsilanes and benzylic electrophiles
| Autor: | Loïc Cornelissen, Olivier Riant, Virginie Cirriez, Sébastien Vercruysse |
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| Přispěvatelé: | UCL - SST/IMCN/MOST - Molecules, Solids and Reactivity |
| Rok vydání: | 2014 |
| Předmět: |
Styrene derivative
Isomerization Unclassified drug Cross coupling reaction Photochemistry Article Catalysis Degradation Stereochemistry Computational chemistry Materials Chemistry Hydrofluoric acid Reaction time Chromatography Tetrabutylammonium Chemistry Hiyama cross coupling reaction Metals and Alloys Silicate General Chemistry Surfaces Coatings and Films Electronic Optical and Magnetic Materials Coupling (electronics) Electrophile Stereospecificity Ceramics and Composites Copper catalyzed Catalyst Copper Palladium Vinylsilane |
| Zdroj: | Chemical Communications, Vol. 50, no. 59, p. 8018-8020 (2014) |
| ISSN: | 1364-548X 1359-7345 |
| DOI: | 10.1039/c4cc02923b |
| Popis: | Allylbenzene derivatives are ubiquitous frameworks in organic chemistry. Herein is described an efficient copper-catalyzed cross-coupling reaction using vinylsilanes and benzyl bromides, leading to the synthesis of allylbenzenes. This methodology allows the use of cis, trans and 1,1′-disubstituted vinylsilanes as well as a large number of sensitive moieties. © the Partner Organisations 2014. |
| Databáze: | OpenAIRE |
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