Synthesis and Chemistry of Bridgehead Allylsilanes. Stereoselective Reactions with Aldehydes

Autor:	Ryan Lauchli, Liang Zhu, John M. Whitney, Kenneth J. Shea
Rok vydání:	2006
Předmět:	Aldehydes Molecular Structure Bicyclic molecule Stereochemistry Chemistry Organic Chemistry Stereoisomerism General Medicine Silanes Ring (chemistry) Biochemistry Catalysis Intramolecular force Stereoselectivity Lewis acids and bases Physical and Theoretical Chemistry
Zdroj:	ChemInform. 37
ISSN:	1522-2667 0931-7597
DOI:	10.1002/chin.200601172
Popis:	A type II intramolecular Diels-Alder reaction provides access to bicyclo[5.3.1] ring systems with an imbedded bridgehead allylsilane. The Lewis acid catalyzed reactions of these compounds with aldehydes proceed efficiently and with control of stereochemistry. [reaction: see text]
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0d73c9ee4a761f234af9f52578271f73 https://doi.org/10.1002/chin.200601172 Zobrazit plný text záznamu Plný text