Investigation of the individual stages of 2-alkylbutadiene polymerization with bis-(π-crotylnickel iodide)—II

Autor:	V.A. Kormer, N.N. Druz, M.I. Lobach, V. A. Vasiliev, A.V. Zak
Rok vydání:	1978
Předmět:	chemistry.chemical_classification Order of reaction Polymers and Plastics Chemistry Iodide Organic Chemistry chemistry.chemical_element General Physics and Astronomy Photochemistry Adduct Nickel Reaction rate constant Polymerization Proton NMR Materials Chemistry Isomerization
Zdroj:	European Polymer Journal. 14:21-24
ISSN:	0014-3057
DOI:	10.1016/0014-3057(78)90146-5
Popis:	Kinetic studies of the stereochemical addition of π-C4D2NiI to 2-methyl-, 2-ethyl- and 2-isopropyl butadienes-1,3 have been carried out using 1H NMR technique. The reaction orders with respect to the nickel complex were found to be close to unity. The rate constants of the formation and the anti-syn isomerization of 1,2-disubstituted π-allyl 1:1 adducts were determined and the activation energies of these reactions calculated.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0d56f83b37b5a6e682c1e0b202189eea https://doi.org/10.1016/0014-3057(78)90146-5 Zobrazit plný text záznamu